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Redox Evolution of Li-Rich Layered Cathode Materials - MDPI
Notably, a representative Li-rich 4d/5d transition metal layered cathode, Li 2 Ru 0.75 Sn 0.25 O 3 , shows highly reversible oxygen redox and stable cycling performance with a similar charge compensation mechanism as in Li 1.2 Ni 0.4 Mn 0.4 O 2 (Figure 7d).
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Physics. Materials Science. Oxides. Covalency does not suppress O2 formation in 4d and 5d Li-rich O-redox cathodes. License. CC BY 4.0. Authors: Robert House. University of Oxford. John-Joseph...
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Structure and electrochemistry of Li-rich 4d- and 5d ... - ResearchGate
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Published: 20 May 2021. Covalency does not suppress O 2 formation in 4d and 5d Li-rich O-redox cathodes. Robert A. House, John-Joseph Marie, Joohyuk Park, Gregory J. Rees, Stefano Agrestini,...
Covalency does not suppress O2 formation in 4d and 5d Li-rich O-redox ...
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Here we show a new strategy to stabilize anionic redox chemistry in 4d-based Li-rich oxides by substituting electropositive 3d transition-metal (TM) species.